Marble Statues And Acid Rain
Sulfur dioxide plus water makes sulfurous acid.
Marble statues and acid rain. Acid deposition also affects human made structures. In exposed areas of buildings and statues we see roughened. Architects chose limestone marble steel and brass as durable materials intended to resist the elements. Acid rain can ruin buildings and statues by stripping away the material and corroding metal that makes up these structures.
Marble like all calcareous rocks is particularly sensitive to degradation by acid chemicals and to weathering. Acid rain is a threat to both natural areas and to our national monuments and memorials. Acid rain effects on buildings. Although many different types of stone have been used for sculpture the most vulnerable to potential acid rain damage are marble and limestone steiger 2015 the former is essentially a recrystallized form of the latter.
Acid precipitation affects stone primarily in two ways. Stone surface material may be lost all over or only in spots that are more reactive. But to their surprise chemical reactions between the acid rain and building materials led to visible deterioration. When sulfurous sulfuric and nitric acids in polluted air react with the calcite in marble and limestone the calcite dissolves.
The most notable effects occur on marble and limestone which are common building materials found in many historic structures monuments and gravestones. Acid rains are one of the main degradation agents for marble artifacts. Ever wondered if it s still around. Many monuments are made from limestone marble and bronze materials that can be altered or slowly dissolved by acid precipitation.
Acid rain contains carbonic nitric and sulfuric acid that are produced by oxidation and dissolution in water of gaseous oxides co 2 no 2 and so 2 present in the air as chemical pollutants. It is well established that either wet or dry deposition of sulfur dioxide significantly increases the rate of corrosion on limestone sandstone and marble. Although these are recognized as highly durable materials buildings and outdoor monuments made of marble and limestone are now being gradually eroded away by acid rain. Sulfur dioxide an acid rain precursor can react directly with limestone in the presence of water to form gypsum which eventually.
Both are composed of calcite caco 3 other types of stone which are composed of silicate minerals such as granite or sandstone are intrinsically more resistant to acid attack. In exposed areas of buildings and statues we see roughened surfaces removal of material and loss of carved details. Marble with its larger crystals and smaller pores can attain a high polish and is thus preferred for monuments and statues. Acid rain has not gone away but it has gotten somewhat better.
How does acid precipitation affect marble and limestone buildings.